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Synthesis, Structure and Photochemistry of Dibenzylidenecyclobutanonesстатья Исследовательская статья
- Авторы: Fomina M.V., Freidzon A.Ya, Kuz'mina L.G., Moiseeva A.A., Starostin R.O., Kurchavov N.A., Nuriev V.N., Gromov S.P.
- Журнал: Molecules
- Том: 27
- Номер: 21
- Год издания: 2022
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Номер статьи: 7602
- DOI: 10.3390/molecules27217602
- Аннотация: A series of symmetrical dibenzylidene derivatives of cyclobutanone were synthesized with the goal of studying the physicochemical properties of cross-conjugated dienones (ketocyanine dyes). The structures of the products were established and studied by X-ray diffraction and by NMR and electronic spectroscopy. All the products had E,E-geometry. The oxidation and reduction potentials of the dienones were determined by cyclic voltammetry. The potentials were shown to depend on the nature, position, and number of substituents in the benzene rings. A linear correlation was found between the difference of the electrochemical oxidation and reduction potentials and the energy of the long-wavelength absorption maximum. This correlation can be employed to analyze the properties of other compounds of this type. Quantum chemistry was used to explain the observed regularities in the electrochemistry, absorption, and fluorescence of the dyes. The results are in good agreement with the experimental redox potentials and spectroscopy data.
- Добавил в систему: Громов Сергей Пантелеймонович
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | 7602.pdf | 6,0 МБ | 22 ноября 2022 [GromovSP] |