Effect of Electrode Morphology on Performance of Ionic Actuators Based on Vat Photopolymerized Membranes

Morozov, O.S.; Ivanchenko, A.V.; Nechausov, S.S.; Bulgakov, B.A.

Авторы: Morozov Oleg S., Ivanchenko Anna V., Nechausov Sergey S., Bulgakov Boris A.
Журнал: Membranes
Том: 12
Номер: 11
Год издания: 2022
Издательство: MDPI Publishing
Местоположение издательства: Basel, Switzerland, Switzerland
Первая страница: 1110
DOI: 10.3390/membranes12111110
Аннотация: Bucky gel electrodes are composed of morphology-determining polyvinylidene difluoride (PVDF) filled with carbon nanotubes (CNT). The electrodes are commonly fabricated via the casting of a CNT dispersion containing PVDF and ionic liquid. In this study, several pore-forming additives such as polyethylene glycol (PEG), dibutyl phthalate (DBP), and the common ionic liquid BMIMBF4 were used to control the morphology of the bucky gel electrodes. The crystalline phase type and content of PVDF in the electrodes were determined by FT-IR and DSC, respectively. SEM revealed a sponge-like structure in the case of the use of BMIMBF4 and a spherulite structure if PEG and DBP were used as additives. A strong influence of morphology on the anisotropic increase in the volume of electrodes upon impregnation with electrolyte was observed. The PEG-based electrode elongated more than the others, while the BMIMBF4-based electrode thickened to a greater extent. Ionic actuators were fabricated to experimentally reveal the effect of electrode morphology on their electromechanical efficiency. A high-precision vat photopolymerization technique was used to fabricate identical ionic membranes and minimize their influence on the properties of the actuators. The electrodes were characterized by the same porosity and electrical capacitance, while the actuators differ significantly in performance. As a result, a simple method of using pore-forming additives made it possible to increase the maximum deformation of bucky gel ionic actuators by 1.5 times by changing the morphology of the electrodes
Добавил в систему: Морозов Олег Сергеевич

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Effect of Electrode Morphology on Performance of Ionic Actuators Based on Vat Photopolymerized Membranesстатья Исследовательская статья

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