Halogen exchange in complexes of hexacoordinate tin (LnCH2)2SnX2 and (LnCH2)2SnY2 containing lactamomethyl n-membered C,O-chelate ligands LnCH2 (n=5–7, X, Y = Cl, Br, I)статья
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Аннотация:Halogen exchange reactions between hexacoordinate tin dihalides (LnCH2)2SnX2 and (LnCH2)2SnY2 (LnCH2 = C,O-chelate n-membered lactamomethyl ligand, n = 5–7, X, Y = Cl, Br, I) produce mixed dihalides (LnCH2)2SnXY. Along with the signals of original complexes, NMR 119Sn spectra of solutions containing two different homodihalides show the third signal with a median chemical shift. The results of NMR monitoring studies, conductivity data and quantum-chemical calculations suggest that mixed dihalides readily form in solutions, although these complexes have not been isolated as individual compounds.
