Synthesis, structure and properties of coordination complexes of tin(II) phthalocyanine and naphthalocyanine with transition metal fragmentsстатья
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Дата последнего поиска статьи во внешних источниках: 20 февраля 2024 г.
Аннотация:Tin(II) can form stable M–Sn bonds yielding coordination complexes with transition metal fragments (M).Coordination complexes of tin and indium porphyrins have mainly been developed to date. We have foundthat such complexes can be obtained with tin phthalocyanines and naphthalocyanines as well. Moreover,such complexes can be obtained not only with neutral metallomacrocycles but also with their radicalanions and dianions. As a result, the range of complexes of such type can be extended by varyingmacrocycles and their charge state as well as by using different transition metal fragments and clusters.During our work, several papers concerning this field of research have been published but somecomplexes still remain unpublished. To provide a more refined general view, we also present newcomplexes obtained in our group. In this review, we discuss different aspects of coordination chemistry oftin(II) macrocycles such as molecular design and synthesis of these compounds, their crystal and molecularstructures, properties and the effect of coordination and reduction on the structure and properties.Possible applications of such compounds are discussed. 29 compounds are considered here among which13 compounds are reported for the first time.