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Kinetics and mechanism of the reactions of ozone with guaiacol, veratrol, and veratrol derivativesстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
- Авторы: Khudoshin A.G., Mitrofanova A.N., Lunin V.V.
- Журнал: Russian Chemical Bulletin
- Том: 57
- Номер: 2
- Год издания: 2008
- Издательство: Springer Nature
- Местоположение издательства: Switzerland
- Первая страница: 283
- Последняя страница: 288
- DOI: 10.1007/s11172-008-0043-6
- Аннотация: The kinetics of the reactions of ozone with compounds modeling structural lignin fragments, viz., phenol, guaiacol, veratrol, veratric aldehyde, and veratric alcohol, was studied. The reaction rate constants were calculated using the mass transfer model for the chemical reaction based on the film theory. The rate constants of the reactions of ozone with compounds of the veratryl series were calculated by the Hammett equation. The major ozonation products of the studied compounds were determined by HPLC. The ozonation mechanism was proposed.
- Добавил в систему: Лунин Валерий Васильевич