The electrochemical synthesis and X-ray single crystal study of Re4O6(OiPr)10 – a new Rhenium(V, VI) cluster with an unprecedented arrangement of metal–metal bondsстатья
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Авторы:Shcheglov Pavel,
Seisenbaeva Gulaim A.,
Drobot Dmitrii V.,
Kessler Vadim G.
Аннотация:The anodic oxidation of rhenium metal in isopropanol at temperatures not exceeding 20°C provides with good yields the crystalline Re4O6(OiPr)10 (I) complex, the molecular structure of which is built up around a practically ideal (Re–Re 2.52–2.54 Å) planar rhombus of metal atoms, being thus connected by five equivalent metal–metal bonds in a system with only six cluster electrons.