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Chemical Transformations of [Pd(OOCMe)4Mn] in the Reactions with 1,10-Phenanthroline and Pivalic Acidстатья
Дата последнего поиска статьи во внешних источниках: 29 января 2024 г.
- Авторы: Sosunov E.A., Maksimova A.D., Yakushev I.A., Ogarkova N.K., Vargaftik M.N., Popova A.S.
- Журнал: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
- Том: 49
- Номер: 12
- Год издания: 2023
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 812
- Последняя страница: 821
- DOI: 10.1134/s1070328423600754
- Аннотация: A series of new Pd–Mn bimetallic acetate and pivalate complexes were synthesized and structurally characterized. The starting [Pd(OOCMe)4Mn] complex reacts with N‑donor ligands such as 1,10-phenanthroline (phen) to give [Pd(OOCMe)4Mn(phen)]⋅MeCN (I) (CCDC no. 2217716). The replacement of acetate bridges in the heterometallic Pd–Mn carboxylate complexes with pivalate bridges was investigated. It was shown that complete replacement of all acetate bridges with pivalate ones can occur both in heterometallic complex I, which contains a ligand coordinated to the second metal atom, to give the compound [Pd(Piv)4Mn(phen)]⋅C6H6 (II) (CCDC no. 2217717), structurally related to the initial acetate complex, and in the acetate complex [Pd(OOCMe)4Mn]. The heterometallic co-crystallized pivalate [Pd(Piv)4Mn⋅2HPiv] (III) (CCDC no. 2217718) formed in the latter case can react with 5-nitro-1,10-phenanthroline to give the complex [Pd(Piv)4Mn(Nphen)] (IV) (CCDC no. 2217719).
- Добавил в систему: Сосунов Егор Александрович