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Photocurrent Kinetics at the Electron-Emission from a Metal into Electrolyte Solution.7. Absolute Rate Constants of CO2 Electrochemical Reduction on Mercuryстатья
- Авторы: Babenko S.D., Benderskii V.A., Krivenko A.G., Kurmaz V.A.
- Журнал: Journal of Electroanalytical Chemistry
- Том: 159
- Номер: 1
- Год издания: 1983
- Издательство: Elsevier Sequoia
- Местоположение издательства: Switzerland
- Первая страница: 163
- Последняя страница: 181
- DOI: 10.1016/S0022-0728(83)80322-2
- Аннотация: The method of laser photoelectronlc emission has been used to measure the oxldation and reduction rate constants of an intermediate of CO2 electrochemical reduction up to a formate on mercury A sharp acceleration of the intermediate reduction occurs at pH < 3.5. It is supposed that in neutral solutions the intermediate is CO(2ads)- which is protonated in acid solutions.
- Добавил в систему: Курмаз Владимир Александрович