Naphthalene and its derivatives hydrogenation for hydrogen storage: Comparative analysis of the role of noble and non-noble metal catalysts – A reviewстатья
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Дата последнего поиска статьи во внешних источниках: 15 мая 2024 г.
Аннотация:The development of low-cost and safe hydrogen storage systems is a priority when creating new energy sources.Storing hydrogen in chemical compounds in which it occurs naturally is the only alternative. Aromatic hydro-carbons, capable of reversible hydrogenation–dehydrogenation reactions, are of the greatest interest amongregenerated hydrogen-containing compounds and can be used for hydrogen storage. Naphthalene, its methylderivatives and the products of hydrogenation have the high storage density among the aromatic hydrocarbons(up to 7.3 wt%) which make it the extremely perspective as liquid hydrogen storage carriers. Therefore, thesynthesis of the compounds with the higher added value (as decalin) is a highly important from scientific point ofview. However, for the building up of “ideal” chemical system of hydrogen storage the development of effectivecatalytic systems with the composition and morphology adopted to the structure of aromatic substrate is highlyneeded. This review discusses the role of the metal in the catalytic hydrogenation of naphthalene and its de-rivatives for hydrogen storage.