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Synthesis of C-Mercuro Derivatives of ortho-Carborane. Crystal Structure of Bis(2-phenyl-ortho-carboran-1-yl)mercuryстатья
- Авторы: Anufriev S.A., Timofeev S.V., Nasyrova D.I., Sivaev I.B., Bregadze V.I.
- Журнал: Russian Journal of Inorganic Chemistry
- Том: 69
- Год издания: 2024
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- DOI: 10.1134/S0036023624600187
- Аннотация: Many carborane derivatives first synthesized during the rapid development of this field of chemistryin the 1960s remained completely uncharacterized by modern spectral and diffraction methods. In this work, a series of C-mercuro derivatives of ortho-carborane 1-PhHg-2-Ph-1,2-C2B10H10 and (2-R-1,2-C2B10H10)2Hg (R = H, Me, Ph) were newly synthesized and characterized by NMR spectroscopy. The molecular crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury was determined by single crystal X-ray diffraction.
- Добавил в систему: Сиваев Игорь Борисович
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