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Hydrodechlorination of Diclofenac in an Aqueous Solution over Pd/ZrO2 and Pd/ZrO2SiO2 Catalystsстатья
Статья опубликована в журнале из списка Web of Science и/или Scopus
- Авторы: Shishova V.V., Lokteva E.S., Maksimov G.S., Maslakov K.I., Kaplin I.Yu, Maksimov S.V., Golubina E.V.
- Журнал: Moscow University Chemistry Bulletin
- Том: 79
- Номер: 3
- Год издания: 2024
- Издательство: Allerton Press Inc.
- Местоположение издательства: United States
- Первая страница: 156
- Последняя страница: 169
- DOI: 10.3103/S0027131424700123
- Аннотация: Pd/ZrO2 and Pd/ZrO2SiO2 catalysts prepared by wet impregnation and reduced with H2 under mild (30°C, aqueous suspension) or harsh (320°C) conditions are compared in the hydrodechlorination of the microecotoxicant diclofenac (DCF) in an aqueous solution at 30°С. According to the TPR and XPS data, the addition of SiO2 to the support reduces the degree of metal-support interaction and facilitates the reduction of palladium. Despite the lower Pd0 fraction, the Pd/ZrO2 catalyst is more active in the batch reactor: after reduction at 320°С, it slightly, and after mild reduction, significantly (7 times), exceeds Pd/ZrO2SiO2 in catalytic activity. XRD and TEM show a wider size distribution of palladium nanoparticles in the Pd/ZrO2 sample, while low-temperature N2 adsorption, XPS, and TPR demonstrated better accessibility of palladium on the Pd/ZrO2 surface due to the reduced decoration by the support components and increased pore size. These features explain the increased activity of Pd/ZrO2. Testing in the flow system demonstrated higher DCF conversion in the presence of catalysts reduced at 320°C and higher stability of Pd/ZrO2SiO2 compared to Pd/ZrO2. The stability is ensured by the increased reducibility of Pd2+ with H2 and by the developed surface of Pd/ZrO2SiO2, which prevents deactivation under the action of HCl released in hydrodechlorination.
- Добавил в систему: Маслаков Константин Игоревич
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