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Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complexстатья
- Авторы: Efimenko Inessa A., Kubasov Alexey S., Ivanova Nina A., Erofeeva Olga S., Demina Ludmila I.
- Журнал: Mendeleev Communications
- Том: 34
- Номер: 5
- Год издания: 2024
- Издательство: Russian Academy of Sciences
- Местоположение издательства: Russian Federation
- Первая страница: 748
- Последняя страница: 750
- DOI: 10.1016/j.mencom.2024.09.040
- Аннотация: A one-step reaction was discovered giving the h3-allylcomplex [Pd(h3-C6H9O)(μ-Cl)]2. The formation of thesubstituted h3-allyl ligand in the complex occurs as a resultof the condensation of acetone at room temperature in asolution containing [Pd(PhCN)2Cl2] and organic acids. Thestructure of the resulting Pdii complex was determined bysingle crystal X-ray diffraction analysis.
- Добавил в систему: Демина Людмила Ивановна