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A Novel Heavy-Atom-Free Approach to the Synthesis of Asymmetric α,α-Ethene-Bridged BODIPY Dimersстатья
Информация о цитировании статьи получена из
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 4 марта 2026 г.
- Авторы: Bykusov Vladislav, Spector Daniil, Beloglazkina Elena, Krasnovskaya Olga
- Журнал: Russian Journal of General Chemistry
- Том: 96
- Номер: 2
- Год издания: 2026
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Номер статьи: 18
- DOI: 10.1134/s1070363225607781
- Аннотация: BODIPY bichromophores are of great interest due to their unique photophysical properties, which significantly distinguish them from BODIPY monomers and open up excellent prospects for their various applica-tions. Thus, ethene/ethylene-bridged BODIPY dimers are usually may be concerned as intramolecular J-aggregates with significant exciton coupling and absorption in the NIR region. However, the synthesis of asymmetric α,α-ethene-bridged BODIPY dimers is limited by Stille cross-coupling reactions, without the possibility of obtaining α,α-ethene-bridged BODIPY dimers. Herein, we propose a novel approach to the synthesis of an asymmetric ethene-bridged α-α BODIPY dimer without cross-coupling reaction, which opens up the possibility of synthesis without the use of expensive cross-coupling reagents from readily available reagents.
- Добавил в систему: Красновская Ольга Олеговна
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