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Cation-Induced Dimerization of Crown-Substituted Phthalocyanines by Complexation with Rubidium Nicotinate As Revealed by X-ray Structural Dataстатья
Статья опубликована в высокорейтинговом журнале
Статья опубликована в журнале из списка Web of Science и/или Scopus- Авторы: Lapkina L.A., Larchenko V.E., Kirakosyan G.A., Tsivadze A.Yu, Troyanov S.I., Gorbunova Yu G.
- Журнал: Inorganic Chemistry
- Год издания: 2017
- Издательство: American Chemical Society
- Местоположение издательства: United States
- DOI: 10.1021/acs.inorgchem.7b01983
- Аннотация: The supramolecular dimeric complex [(μ-oxo)bis(tetra-15-crown-5-phthalocyaninato)(nicotinato)aluminum(III)]tetra(rubidium) bis(nicotinate) was prepared. A single-crystal X-ray diffraction study of {[Rb4(NicAl(15C5)4Pc)2(μ-O)]2+(Nic−)2}·2.36HNic·11H2O demonstrated that two molecules of the aluminum crown-phthalocyaninate nicotinate are connected through an Al−O−Al bridge supported by sandwiching of crown ether moieties by Rb+ cations.
- Добавил в систему: Троянов Сергей Игоревич