Volatile Compounds of Lanthanides

Авторы: Drozdov A., Kuzmina N.
Сборник: Comprehensive Inorganic Chemistry
Серия: II
Том: 2
Глава в коллективной монографии
Год издания: 2012
Место издания: Elsevier
Первая страница: 511
Последняя страница: 534
DOI: 10.1016/B978-0-08-097774-4.00223-0
Аннотация: This chapter gives a brief summary of volatile rare earth metal compounds, including halides, alkoxides, siloxides, borohydrides, organometallic compounds, and, mainly, diketonates. Volatility data for the following main classes (types) of lanthanide β-diketonates are summarized: (1) homoligand compounds, [Ln(dik)3]x (x ≥ 1), including Ce(dik)4; (2) heteroligand compounds, [Ln(dik)3(Q)n] (also named mixed ligand compounds), with Q neutral donor ligands, including neutral nickel(II) complexes; and (3) tetrakis-β-diketonates, M[Ln(dik)4] (M+ – alkali or organic cation). Examples of volatile homoligand β-ketoiminates and mixed-ligand dialkyldithiocarbamates as well as carboxylates are listed. The factors that regulate the volatility are discussed.
Добавил в систему: Дроздов Андрей Анатольевич

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