Phase transitions and fluctuations in classical statistical mechanicsстатья
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Дата последнего поиска статьи во внешних источниках: 18 февраля 2018 г.
Аннотация:It is shown that allowance for fluctuations leads to the appearance of additional terms in the Hamiltonian of the system and in the thermodynamic parameters of the substance. As a result, it becomes possible to describe the critical phenomena and phase transitions of liquid-vapor within classical statistical mechanics (without taking into account fluctuations, this is impossible).