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Analysis of group theoretical periodic systems of molecules using tabulated dataкнига
- Авторы: Carlson C.M., Hefferlin R.A., Zhuvikin G.V.
- Год издания: 1995
- Место издания: Southern College, Physics Department Collegedale, TN, USA
- Объём: 66 страниц
- Монография
- Аннотация: The second of a series, this report substantiates the theory given previously by substituting tabulated data for observable operator expectation values of molecular-state-vector multiplets corresponding to the groups SO(3)xSU(2)s, SO(4)xSU(2)s, and SO(2,1). We plot the data on the principle axes of the multiplets using various orders of observable operators and substitutions from expectation-value identities. The generally well-behaved plots for the first and third symmetries demonstrate a similarity between various N-atomic species, one example of invariance for different properties, periodicity with respect to changes in the row numbers of the constituent atoms, and inclusive similarity in many cases where the independent-variable ranges of one multiplet lie within those of another multiplet. We examine the relative successes and failures of several expectation-value substitutions and find that plots for the symmetry group SO(4)xSU(2)s are very poorly behaved.
- Добавил в систему: Жувикин Георгий Викторович