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ADSORPTION OF GASES, VAPORS AND LIQUIDSкнига
- Автор: Tolmachev A.M.
- Год издания: 2012
- Место издания: Publishing Group Ltd "Granica" Moscow
- Объём: 214 страниц
- ISBN: 978-5-94691-503-8
- Аннотация: The book analyzes in detail the description of the adsorption equilibrium at the macro- and microporous adsorbents, both within the “Gibbs method of excess”, and as part of the “method of the full content”. In the latter case the discussion held on the basis of the thermodynamic theory of stoichiometric adsorption of individual substances and binary and multicomponent solutions developed by the author. The methods of the theoretical (a priori) calculation of the adsorption equilibria and description of the “absolute” and “excessive” adsorption isotherms of gases, vapors, and the components of binary solutions of nonelectrolytes by different equations, obtained in the framework of the phenomenological, lattice and empirical models, are detailed. Methods for the quantitative description of the adsorption isotherms and topological analysis of supramolecular structures of adsorbates on microporous active carbons by molecular dynamics simulations are discussed. A comparison of numerical and physical experiments proved the possibility of using the equations of the theory of volume filling of micropores (Dubinin-Radushkevich, Dubinin-Astakhov), the equations of lattice models and others at supercritical temperatures. The adsorption Databank developed under the author’s supervision is presented. The book analyzes in detail the description of the adsorption equilibrium at the macro- and microporous adsorbents, both within the “Gibbs method of excess”, and as part of the “method of the full content”. In the latter case the discussion held on the basis of the thermodynamic theory of stoichiometric adsorption of individual substances and binary and multicomponent solutions developed by the author. The methods of the theoretical (a priori) calculation of the adsorption equilibria and description of the “absolute” and “excessive” adsorption isotherms of gases, vapors, and the components of binary solutions of nonelectrolytes by different equations, obtained in the framework of the phenomenological, lattice and empirical models, are detailed. Methods for the quantitative description of the adsorption isotherms and topological analysis of supramolecular structures of adsorbates on microporous active carbons by molecular dynamics simulations are discussed. A comparison of numerical and physical experiments proved the possibility of using the equations of the theory of volume filling of micropores (Dubinin-Radushkevich, Dubinin-Astakhov), the equations of lattice models and others at supercritical temperatures. The adsorption Databank developed under the author’s supervision is presented.
- Добавил в систему: Толмачев Алексей Михайлович